Tatsuya Tsuboi, Hideki Wada
The submersible Shinkai 6500 located a large limestone block on the landward slope of the Palau Trench at approximately 6500 m depth, significantly deeper than the lysocline. This study aims to document the deep-sea carbon flux from the limestone block to seawater. The Sr isotope age of the limestone block indicates it formed in the middle and late Miocene, approximately 13–7 million years ago. Accelerator mass spectrometry measurements of the 14C of dissolved inorganic carbon (DIC) extracted from seawater collected around the limestone block yielded values as low as −295‰. Through isotope mass-balance calculations, we estimated the flux of limestone-derived carbonate ions to deep seawater, revealing that limestone-derived carbonate ions contribute up to 6.7% of the bottom water DIC concentration. The annual DIC flux from the limestone block is estimated to be 2.1 (±1.4) × 10^8 mol/y or 2.5 (±1.7) × 10^9 gC/y. These findings demonstrate a significant carbon flux into the deep-sea environment and represent the first example of carbonate dissolution occurring below the lysocline.
@article{05fddb67-ec57-4ef7-811b-1a19978a4c0c,
title={Deep-sea limestone block as a source of14C-depleted dissolved inorganic carbon at the Palau Trench},
author={Tatsuya Tsuboi and Hideki Wada},
year={2013},
language={en}
}TY - JOUR TI - Deep-sea limestone block as a source of14C-depleted dissolved inorganic carbon at the Palau Trench AU - Tatsuya Tsuboi AU - Hideki Wada PY - 2013 LA - en ER -
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