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Significance of hydrated radius and hydr

Berrin Tansel, John Sager

2026ennanofiltrationionic permeabilityhydration shellsdead endcross flow

Abstract

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The aerobic rotational membrane system (ARMS) is one of the water recovery and recycling processes considered for use during long space missions. The purpose of this study was to investigate the permeability characteristics of ions present in the ARMS effluent through a nanofiltration membrane. Experiments were conducted in stirred dead end and cross flow filtration modes to evaluate the effectiveness of the nanofiltration process to remove dissolved solids. The rejection characteristics of the ions were evaluated in relation to ionic hydrated radius, hydration number, and ionic viscosity parameters. Permeability of ions through the nanofiltration membrane showed a strong correlation with their hydrated radii. The ions with relatively smaller crystal radii (i.e., Mg2+ and Ca2+) demonstrated higher hydration numbers and larger hydrated radii, leading to their effective removal by both filtration modes, particularly dead end filtration. Conversely, ions with larger crystal radii (i.e., K+ and Na+) exhibited weaker hydration shells, allowing them to detach more easily during membrane passage. Results consistently indicated higher permeation rates in dead end mode compared to cross flow mode operated at the same pressure.

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Cite This Work

@article{0f6f93c1-2d31-4ab0-9886-50b10bcbaa2b,
  title={Significance of hydrated radius and hydr},
  author={Berrin Tansel and John Sager},
  year={2026},
  language={en}
}
TY  - JOUR
TI  - Significance of hydrated radius and hydr
AU  - Berrin Tansel
AU  - John Sager
PY  - 2026
LA  - en
ER  -

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