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Green recovery of vanadium from spent vanadium catalyst from sulfuric acid production

Ashraf A. Shaltout, Rabeia S. F. El-Hallag

2026envanadiumrecoverycitric acidspent catalystsulfuric acid

Abstract

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Research on extracting secondary raw materials from hazardous waste is gaining global importance, particularly regarding spent catalysts containing heavy metals which pose environmental threats. This study aims to recover vanadium from spent catalysts discharged during sulfuric acid production, which contain 4.66% V2O5. A series of experiments were conducted using four different leaching acids: tartaric, oxalic, acetic, and citric acids, to assess their effectiveness under varying conditions. Temperature, reagent concentration, leaching duration, and solid/liquid ratio were systematically tested. The results demonstrated that under optimal conditions, an impressive 95% of vanadium was recovered through citric acid leaching, utilizing specific parameters of a 2% solid/liquid ratio, 1 M citric acid at 70 °C, pH adjustments, and a leaching duration of 120 minutes. The findings underscore the significant potential for recovering vanadium pentoxide from spent vanadium catalysts that are typically generated in the sulfuric acid industry in Egypt.

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Cite This Work

@article{101a6f44-0b03-425c-9860-a5a0bef9c166,
  title={Green recovery of vanadium from spent vanadium catalyst from sulfuric acid production},
  author={Ashraf A. Shaltout and Rabeia S. F. El-Hallag},
  year={2026},
  language={en}
}
TY  - JOUR
TI  - Green recovery of vanadium from spent vanadium catalyst from sulfuric acid production
AU  - Ashraf A. Shaltout
AU  - Rabeia S. F. El-Hallag
PY  - 2026
LA  - en
ER  -

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