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2025 Shalchian Nitric acid purification kinetics of molybdenite

Hossein Shalchian, Payam Ghorbanpour

2026enmolybdenitenitric acidselective leachingcopper removaliron removalkinetic modeling

Abstract

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The selective removal of impurities from molybdenite concentrates is crucial for producing high-purity molybdenum products. In this study, the purification of molybdenite concentrate was investigated using nitric acid as both a leaching medium and oxidizing agent. Leaching experiments were carried out under various conditions of temperature (22–78 ◦C) and nitric acid concentration (0.12–0.48 M). The results demonstrated that while molybdenite remained mostly undissolved, copper and iron were effectively leached, with near-complete removal at 78 ◦C in 0.24 M HNO3 after 6 h. Compared with other acid systems, nitric acid leaching experiments in this study demonstrated higher efficiency and selectivity under relatively moderate conditions of concentration and temperature. Kinetic analyses were performed based on the shrinking core model, indicating that temperature exerted the strongest effect on Mo dissolution, while acid concentration showed a lower effect in comparison with temperature.

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Cite This Work

@article{4610231b-0c82-4b65-87b7-b33845fc9464,
  title={2025   Shalchian   Nitric acid purification kinetics of molybdenite},
  author={Hossein Shalchian and Payam Ghorbanpour},
  year={2026},
  language={en}
}
TY  - JOUR
TI  - 2025   Shalchian   Nitric acid purification kinetics of molybdenite
AU  - Hossein Shalchian
AU  - Payam Ghorbanpour
PY  - 2026
LA  - en
ER  -

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