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Doping Calcia and Yttria into Zirconia O (1)

Fitri Rahmawati, Bambang Prijamboedi

2026enionic conductivityzirconiayttriacalciaelectrolyte

Abstract

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Zirconia has been prepared from Zircon concentrate by caustic fusion methods. Zircon is a by product from tin ore concentration plant at Bangka island of Indonesia. Ytria Stabilized-Zirconia (YSZ) was prepared by introducing the 8 % mol yttrium oxide into zirconia and sintered at 1500 C for 5 hours. In order to obtain constant oxygen vacancy of 8 % mol in Zirconia, an appropriate amount of Yttria and Calcia were introduced into Zirconia and the mixtures were heated at 1350 oC for 5 hours. Elemental composition was determined by SEM/EDX and XRF and lattice parameters were determined using X-ray diffraction method. Ionic conductivity was measured by complex impedance spectroscopy. The results show that doping of Yttria into Zirconia (YSZ) and Calcia-Yttria into Zirconia (CYZ) allows phase transformation of Zirconia from tetragonal with space group P42/nmc into cubic Fm3m and enhance the ionic conductivity. However, the prepared materials are porous and have not met the requirement for the electrolyte material yet.

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Cite This Work

@article{4b1f22a3-a5f6-4788-a1a1-8fa4e75937c2,
  title={Doping Calcia and Yttria into Zirconia O (1)},
  author={Fitri Rahmawati and Bambang Prijamboedi},
  year={2026},
  language={en}
}
TY  - JOUR
TI  - Doping Calcia and Yttria into Zirconia O (1)
AU  - Fitri Rahmawati
AU  - Bambang Prijamboedi
PY  - 2026
LA  - en
ER  -

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