G. Garg, S. Bobeva
Starting from pure metals and sulphur in evacuated silica tubes single crystals of Cu5.479Fe2.9Sn13.1S32 have been obtained by quenching from 680°C. It crystallizes in the Fd3m space group with a = 10.3022 (6) Å. The atomic parameters, occupancies, and anisotropic thermal parameters were refined to give a final R-value of 0.0116. The 119Sn Mössbauer study shows the presence of Sn (IV) in an octahedral environment and 57Fe Mössbauer indicates the presence of Fe (II) in an octahedral environment, statistically distributed in both low- and high-spin states. These findings enhance the understanding of the electronic structure and behavior of cation-deficient thiospinels, which have potential applications in battery technology due to their favorable ion intercalation properties.
@article{5e9fad65-8ec1-4665-9fb2-17d5b304ef05,
title={Single crystal structure and Mossbauer s},
author={G. Garg and S. Bobeva},
year={2026},
language={en}
}TY - JOUR TI - Single crystal structure and Mossbauer s AU - G. Garg AU - S. Bobeva PY - 2026 LA - en ER -
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