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Electrochemical and physical characteris

Z. S. Misindo, V. Sibanda

2026enelectrowinningdimensionally stable anodeselectrochemical behaviourlead anodes

Abstract

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The suitability of various dimensionally stable anodes (DSA®) was investigated in comparison to the conventional lead alloy anodes in the electrowinning of copper. DSA® plate and mesh specimens of composition Ti-(70%) IrO2/(30%) Ta2O5 and lead–(6%) antimony were evaluated. The electrochemical behaviour of these anodes was studied by carrying out open circuit potential measurements, galvanostatic chronopotentiometry, cyclic voltammetry and chronochemistry. Physical characterisation was done using a scanning electron microscope. It was observed that the DSA® plate anode exhibited the highest corrosion resistance followed by the DSA® mesh and lead anodes, respectively. The results also showed that during copper electrowinning using lead anodes, dissolution of the anode occurs while for both DSA®'s marginal loss of coating was observed. The lead anode had the highest anodic potential followed by the DSA® plate and mesh anodes, respectively. Overall, it was demonstrated that the DSA® plate anode is the most suitable anode for copper electrowinning.

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Cite This Work

@article{6b3c71a4-6a6b-4857-b07c-4207d543a721,
  title={Electrochemical and physical characteris},
  author={Z. S. Misindo and V. Sibanda},
  year={2026},
  language={en}
}
TY  - JOUR
TI  - Electrochemical and physical characteris
AU  - Z. S. Misindo
AU  - V. Sibanda
PY  - 2026
LA  - en
ER  -

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