Metallographic and Extraction Replica Methods for Characterization of Tungsten Heavy Alloy: H13 Clads

Tungsten heavy alloys are used in demanding high pressure die casting applications due to their high temperature strength, high thermal conductivity, and low thermal expansion. High cost limits applications to small sintered die inserts and manual gas tungsten arc weld repairs. A new tungsten heavy alloy consumable, Anviloy wire, was developed for automated cladding of hot work tool steel dies. Literature regarding characterization of tungsten heavy alloy die steel clads was lacking. Understanding base metal dilution effect on clad microstructure is critical but required new sample preparation methods. An Anviloy wire-H13 clad was made using hot wire gas tungsten arc cladding and analyzed with metallography. Samples were found to have grain boundary M6C carbide phase as-welded with the help of an alkaline sodium picrate etchant. An isothermally aged arc crucible melted sample of the same composition was characterized using metallography, scanning electron microscopy, and transmission electron diffraction. The clad representative arc crucible melted sample was subjected to isothermal aging at 725°C for 100 hours. Isothermal aging resulted in precipitation of a high volume fraction of intermetallic platelets. Using a new carbon extraction replica sample preparation method involving two chemical polishing steps, transmission electron diffraction of precipitates indicated they were mu phase intermetallic.