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A novel Ni/ceria-based anode for metal-supported solid oxide fuel cells

Veronika A. Rojek-W€ockner, Alexander K. Opitz

2016ensolid oxide fuel cellsanodeNi/ceriaperformanceimpedance

Abstract

Language:

For optimization of ageing behavior, electrochemical performance, and sulfur tolerance of metal-supported solid oxide fuel cells a new anode concept is introduced, which is based on a Ni/GDC cermet replacing the established Ni/YSZ anodes. In the present work optimized processing parameters compatible with MSC substrates are specified by doing sintering studies on pressed bulk specimens and on real porous anode structures. The electrochemical performance of the Ni/GDC anodes was characterized by means of symmetrical electrolyte supported model-type cells. In this study, three main objectives are pursued. Firstly, the effective technical realization of the Ni/GDC concept is demonstrated. Secondly, the electrochemical behavior of Ni/GDC porous anodes is characterized by impedance spectroscopy and compared with the current standard Ni/YSZ anode. Further, a qualitative comparison of the sulfur poisoning behavior of both anode types is presented. Thirdly, preliminary results of a successful implementation of the Ni/GDC cermet into a metal-supported single cell are presented.

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Cite This Work

@article{86cdbf6a-30e3-4806-850e-cfed85b3871a,
  title={A novel Ni/ceria-based anode for metal-supported solid oxide fuel cells},
  author={Veronika A. Rojek-W€ockner and Alexander K. Opitz},
  year={2016},
  language={en}
}
TY  - JOUR
TI  - A novel Ni/ceria-based anode for metal-supported solid oxide fuel cells
AU  - Veronika A. Rojek-W€ockner
AU  - Alexander K. Opitz
PY  - 2016
LA  - en
ER  -

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