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Effects of saccharin and quaternary ammonium chlorides on the electrodeposition of nickel from a Watts-type electrolyte

Aleksander Ciszewski, Szymon Posluszny

2004enelectrodepositionnickelsaccharinquaternary ammoniumadditives

Abstract

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The effect of the presence of quaternary ammonium chlorides (QACl) and saccharin on various electrodeposition parameters for nickel deposition on a stainless steel cathode from a Watts-type plating bath was investigated. The parameters included cathodic current efficiency, throwing power of the bath, cathodic polarization, crystal orientation, and quality of the deposit. The following additives were investigated: saccharin, 1-alkyloxymethyl 3-benzyl imidazolium chlorides, decyloxymethyl 3-alkyl imidazolium chlorides, cycloheksyloxymethyl 3-alkyl imidazolium chlorides, benzyl-dimethyl-alkyl ammonium chloride, benzyloxymethyl-dimethyl-alkyl ammonium chlorides, and benzyl-dimethyl-alkyloxymethyl ammonium chlorides. The results indicated that only one type of QACl fulfilled all requirements to be acceptable, namely: benzyl-dimethyl-alkyloxymethyl chlorides, and especially benzyl-dimethyl-buthyloxymethyl chloride. The mechanism of the action of this additive has also been discussed.

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Cite This Work

@article{87967039-9be1-4027-bf1f-3f92c8658d86,
  title={Effects of saccharin and quaternary ammonium chlorides on the electrodeposition of nickel from a Watts-type electrolyte},
  author={Aleksander Ciszewski and Szymon Posluszny},
  year={2004},
  language={en}
}
TY  - JOUR
TI  - Effects of saccharin and quaternary ammonium chlorides on the electrodeposition of nickel from a Watts-type electrolyte
AU  - Aleksander Ciszewski
AU  - Szymon Posluszny
PY  - 2004
LA  - en
ER  -

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