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Formation of RuO OH 2 on RuO 2 Based Ele

Lars-Åke Näslund, Arni Sigurdur Ingason

2026enhydrogen evolutionruthenium dioxide coatingsxpsxrdphase transformation

Abstract

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The catalytic and durable electrode coating of ruthenium dioxide (RuO₂), applied on nickel (Ni) substrates, is today utilized as electrocatalytic cathodes for hydrogen production, e.g., in the chlor-alkali process and alkaline water electrolysis. The drawback is, however, the sensitivity to reverse currents obtained during power shutdowns, e.g. at maintenance, where the RuO₂-based electrodes can be severely damaged unless polarization rectifiers are employed. Through the material characterization techniques X-ray diffraction and X-ray photoelectron spectroscopy we can now reveal that RuO₂ coatings, when exposed to hydrogen evolution at industrially relevant conditions, transforms into ruthenium oxyhydroxide (RuO(OH)₂). The study further shows that as the hydrogen evolution proceeds the formed RuO(OH)₂ reduces to metallic ruthenium (Ru).

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Cite This Work

@article{8ad826b4-a3be-4571-a76c-8032d0110f3a,
  title={Formation of RuO OH 2 on RuO 2 Based Ele},
  author={Lars-Åke Näslund and Arni Sigurdur Ingason},
  year={2026},
  language={en}
}
TY  - JOUR
TI  - Formation of RuO OH 2 on RuO 2 Based Ele
AU  - Lars-Åke Näslund
AU  - Arni Sigurdur Ingason
PY  - 2026
LA  - en
ER  -

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