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Copper nickel superalloys as inert alloy

Zhongning Shi, Junli Xu

2026enaluminum electrolysisinert anodescopper nickel alloysoxidation resistancecorrosion resistancesuperalloys

Abstract

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This study investigates the effectiveness of copper-nickel superalloys, specifically Cu-Ni-Al, Cu-Ni-Fe, and Cu-Ni-Cr, as anodes for aluminum electrolysis. The primary objective was to assess their corrosion resistance in acidic molten salt electrolytes and oxidation rates in various atmospheres including air and oxygen. A series of tests conducted at temperatures ranging from 600°C to 900°C demonstrated that the Cu-Ni-Al alloy exhibited the best corrosion and oxidation resistance among the tested anodes. In comparison, the Cu-Ni-Fe alloy also displayed notable corrosion resistance, while the Cu-Ni-Cr alloy showed poor performance under similar conditions. Notably, the performance of the Cu-Ni-Al anode was significantly influenced by the concentration of alumina within the cryolite molten salt. The findings advocate further research into the potential of Cu-Ni-Al and Cu-Ni-Fe as inert alloy anodes, emphasizing their suitability for high-temperature and corrosive environments critical for aluminum electrolysis applications.

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Cite This Work

@article{94fdfb80-1d97-4512-98e8-91ec4bbdab79,
  title={Copper nickel superalloys as inert alloy},
  author={Zhongning Shi and Junli Xu},
  year={2026},
  language={en}
}
TY  - JOUR
TI  - Copper nickel superalloys as inert alloy
AU  - Zhongning Shi
AU  - Junli Xu
PY  - 2026
LA  - en
ER  -

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