Jian-cheng YU, Bao-zhong MA
The loss pathways of Ni and Co during Al and Sc enrichment were analyzed in the HNO3 leach liquor of saprolitic laterite ore. Although over 99% of Al and Sc can be enriched, about 40% of Ni and Co are also lost. The adsorption of Al−Sc precipitate is an important cause of Ni and Co loss. Subsequently, the precipitation behavior of metal ions in different nitrate solutions was studied. The results confirm that Ni2+ and Co2+ do not hydrolyze to form their respective hydroxides. Ni2+, Co2+, and Mg2+ can form composite hydroxides with precipitated Al(OH)3, decreasing the pH at which Ni2+ and Co2+ begin to precipitate, causing their co-precipitation loss. A high Mg2+ concentration enhances the formation of these composite hydroxides. Finally, titration curves for different nitrate systems were determined, further demonstrating the formation of Me−Al composite hydroxides and revealing a formation trend of Mg−Al > Co−Al > Ni−Al.
@article{971a700f-20cb-49b2-9ff0-c41f3c79b470,
title={Loss behavior of Ni and Co during Al and Sc enri 2025 Transactions of Nonfer},
author={Jian-cheng YU and Bao-zhong MA},
year={2026},
language={en}
}TY - JOUR TI - Loss behavior of Ni and Co during Al and Sc enri 2025 Transactions of Nonfer AU - Jian-cheng YU AU - Bao-zhong MA PY - 2026 LA - en ER -
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