PDF

Elimination of a pollution associated wi

JIANG Xiaojun, CHEN W enchao

2026enchromium platingchromic acidtrivalent chromiumelectro-depositionion exchange membraneanode materials

Abstract

Language:

A method using trivalent chromium has been used to replace hexavalent chromium for the electro-deposition of chromium. Using a tri-chamber bath system various anodic materials and membranes were evaluated to minimize the production of environmentally and health damaging chromic acid. By measuring the absorbance of Cr(VI) at 640 nm, the results indicate that the use of a titanium plated ruthenium (Ti-Ru) anode produces the least amount of chromic acid byproduct compared to lead-gold alloy and graphite anodes. The concentration of Cr(VI) in the immediate vicinity of the Ti-Ru anode decreased from 0.389 mg/L to 0 during a 40-min deposition period. The use of a NafionTM quaternary cation exchange membrane portioning the buffer and anode selectively prevented Cr(III) from entering the anode compartment whilst allowing the migration of H+ to maintain overall voltaic continuity. It has been demonstrated that the use of a Ti-Ru anode with a NafionTM membrane can eliminate the production of chromic acid associated with the electro-deposition of chromium plate thereby preventing its health damaging exposure to plant operators and preventing discharge of Cr(VI) into the environment. Addition of a surfactant improved current efficiency by 34.7%.

Download

Cite This Work

@article{a3a2f133-a79f-4ba6-8249-c2ba3c1c5193,
  title={Elimination of a pollution associated wi},
  author={JIANG Xiaojun and CHEN W enchao},
  year={2026},
  language={en}
}
TY  - JOUR
TI  - Elimination of a pollution associated wi
AU  - JIANG Xiaojun
AU  - CHEN W enchao
PY  - 2026
LA  - en
ER  -

Similar Items

Optimization of Integrated Steel Plant R

This paper addresses the challenge of assessing the feasibility of wind power plant projects at sites with insufficient or no local historic wind data

2025enPDF

Design for Recovery of Precious and Base

2026enPDF

Electrochemical techniques for a cleaner

Important advances in electrochemical engineering technology over the last three decades have fostered the development of a lternative methods to alle

2026enPDF

Environmental and Human Health Risks Ass

2026enPDF

The Recovery of Precious and Base Metals

Increasing volumes of waste printed circuit boards from obsolete electronic equipment posed escalating environmental risks and resource losses due to

2026enPDF

Treatment of manufacturing scrap TV boar

The leachability tests for manufacturing scrap TV boards (STVB) have indicated the release of metals beyond the limit levels with potential problems f

2026enPDF