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Single-step treatment of 2,4-dinitrotoluene via zero-valent metal reduction and chemical oxidation

J. Mathew Thomas, Rafael Hernandez

2007ennitroaromaticreductionoxidationwater treatmentzero-valent iron

Abstract

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Many nitroaromatic compounds (NACs) are considered toxic and potential carcinogens. The purpose of this study was to develop an integrated reductive/oxidative process for treating NACs contaminated waters. The process consists of the combination of zero-valent iron and an ozonation based treatment technique. Corrosion promoters are added to the contaminated water to minimize passivation of the metallic species. Water contaminated with 2,4-dinitrotoluene (DNT) was treated with the integrated process using a recirculated batch reactor. It was demonstrated that addition of corrosion promoters to the contaminated water enhances the reduction of 2,4-DNT with zero-valent iron. The addition of corrosion promoters resulted in 62% decrease in 2,4-DNT concentration to 2,4-diaminotoluene. The data shows that iron reduced the 2,4-DNT and ozone oxidized these products resulting in a 73% removal of TOC and a 96% decrease in 2,4-DNT concentration.

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Cite This Work

@article{ba6da0c9-8cba-4597-9cba-9f0404142631,
  title={Single-step treatment of 2,4-dinitrotoluene via zero-valent metal reduction and chemical oxidation},
  author={J. Mathew Thomas and Rafael Hernandez},
  year={2007},
  language={en}
}
TY  - JOUR
TI  - Single-step treatment of 2,4-dinitrotoluene via zero-valent metal reduction and chemical oxidation
AU  - J. Mathew Thomas
AU  - Rafael Hernandez
PY  - 2007
LA  - en
ER  -

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