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Hydrometallurgical Leaching of Copper Flash Furnace Electrostatic Precipitator Dust for the Separation of Copper from Bismuth and Arsenic

Michael Caplan, Joseph Trouba, Corby Anderson, Shijie Wang

2021encopper processing; copper leaching; copper bearing dusts

Abstract

Language:

Flash furnace electrostatic precipitator dust (FF-ESP dust) is a recycle stream in some primary copper production facilities. This dust contains high amounts of copper. In some cases, the FF-ESP dust contains elevated levels of bismuth and arsenic, both of which cause problems during the electrorefining stages of copper production. Because of this, methods for separation of copper from bismuth and arsenic in FF-ESP dust are necessary. Hydrometallurgical leaching using a number of lixiviants, including sulfuric acid, sulfurous acid, sodium hydroxide, and water, were explored. Pourbaix diagrams of copper, bismuth, and arsenic were used to determine sets of conditions which would thermodynamically separate copper from bismuth and arsenic. The data indicate that water provides the best overall separation between copper and both bismuth and arsenic. Sodium hydroxide provided a separation between copper and arsenic. Sulfurous acid provided a separation between copper and bismuth. Sulfuric acid did not provide any separations between copper and bismuth or copper and arsenic.

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Cite This Work

@article{d80485a5-9c65-47fd-a22d-23939fcc83c4,
  title={Hydrometallurgical Leaching of Copper Flash Furnace Electrostatic Precipitator Dust for the Separation of Copper from Bismuth and Arsenic},
  author={Michael Caplan and Joseph Trouba and Corby Anderson and Shijie Wang},
  year={2021},
  language={en}
}
TY  - JOUR
TI  - Hydrometallurgical Leaching of Copper Flash Furnace Electrostatic Precipitator Dust for the Separation of Copper from Bismuth and Arsenic
AU  - Michael Caplan
AU  - Joseph Trouba
AU  - Corby Anderson
AU  - Shijie Wang
PY  - 2021
LA  - en
ER  -

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