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UNINTENTIONAL CEMENTATION IN THIOUREA LEACHING

Cesar A. Urbano, Jr., Gretchen T. Lapidus

2014ensilverthiourealeachingcementationhydrometallurgy

Abstract

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A series of experiments examined silver extraction from a high-grade sulfide concentrate employing thiourea solution. Thiourea was initially oxidized with hydrogen peroxide (H2O2) to form formamidine disulfide (FADS) and used to extract silver from the as-received concentrate and after various pretreatments. Very low recoveries (~30%) were obtained with the as-received concentrate due to competitive cementation reactions by metallic iron and easily oxidizable copper phases. Over 80% Ag recovery was obtained when the concentrate was pretreated to remove this iron and copper. The results suggest that an oxidative acid pretreatment of this concentrates significantly improves silver recovery upon leaching with thiourea.

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Cite This Work

@article{ea8e045f-ea91-493e-97cb-b25e7d3da3a1,
  title={UNINTENTIONAL CEMENTATION IN THIOUREA LEACHING},
  author={Cesar A. Urbano and Jr. and Gretchen T. Lapidus},
  year={2014},
  language={en}
}
TY  - JOUR
TI  - UNINTENTIONAL CEMENTATION IN THIOUREA LEACHING
AU  - Cesar A. Urbano
AU  - Jr.
AU  - Gretchen T. Lapidus
PY  - 2014
LA  - en
ER  -

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