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Two phase electrolysis process modelling

P. Mandin, H. Roustan

2026enelectrolysisgas bubbleselectrochemical cellshydrodynamicsnumerical modellingmultiphase flow

Abstract

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During two-phase electrolysis for hydrogen, aluminium or fluor production, there are bubbles created at electrodes which imply significant hydrodynamic acceleration along with important electrical properties and disturbances in electrochemical processes. This study addresses the lack of local modelling in two-phase electrolysis, highlighting the need for better understanding of effects like the anode effect, which significantly impacts process efficiency. The objective of this work is to present a comprehensive modelling and numerical simulation approach to gas production, ranging from the single bubble scale to the macroscopic electrochemical cell scale. The study emphasizes the interaction between bubble motion, hydrodynamic properties, species transport, and electrical performance, noting that the presence of bubbles alters both global and local properties, including current density distribution within the electrolysis cell. The work includes theoretical modelling on both scales and examines performance changes observed during the two-phase electrolysis processes.

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Cite This Work

@article{f0415e5e-a6b4-446f-9da2-01b0bd31fdc0,
  title={Two phase electrolysis process modelling},
  author={P. Mandin and H. Roustan},
  year={2026},
  language={en}
}
TY  - JOUR
TI  - Two phase electrolysis process modelling
AU  - P. Mandin
AU  - H. Roustan
PY  - 2026
LA  - en
ER  -

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